Highly diastereo- and enantioselective intramolecular amidation of saturated C-H bonds catalyzed by ruthenium porphyrins.
نویسندگان
چکیده
منابع مشابه
Formation of C-C bonds via ruthenium-catalyzed transfer hydrogenation().
Ruthenium-catalyzed transfer hydrogenation of diverse π-unsaturated reactants in the presence of aldehydes provides products of carbonyl addition. Dehydrogenation of primary alcohols in the presence of the same π-unsaturated reactants provides identical products of carbonyl addition. In this way, carbonyl addition is achieved from the alcohol or aldehyde oxidation level in the absence of stoich...
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ورودعنوان ژورنال:
- Angewandte Chemie
دوره 41 18 شماره
صفحات -
تاریخ انتشار 2002